Biofuels. Sequential volarization of waste coffee grounds to Biodiesel Bioethanol and solid fuel

Master's Thesis from the year 2014 in the subject Energy Sciences course: Biofuels language: English abstract: In this study the utilization of waste coffee residue for biodiesel production its solid byproduct after oil extraction for bioethanol production as well as the second byproduct after bioethanol production for solid fuel and compost production was investigated. For the study waste coffee residue sample was collected from TOMOCA PLC Addis Ababa Ethiopia. The oil was then extracted using n-hexane and resulted in oil yield of 19.73 %w/w. The biodiesel was obtained by a two-step process i.e. acid catalyzed esterification followed by base catalyzed transesterification using catalysts sulfuric acid and sodium hydroxide respectively. The conversion after esterification of waste coffee residue oil in to biodiesel was about 80.4%. Various parameters that are essential for biodiesel quality were evaluated using the American Standard for Testing Material (ASTM D 6751- 09). The results obtained for kinematic viscosity (5.3 mm²/s) carbon residue (0.033%) flash point (222°C) ash content (0.0123%) water and sediment (<0.01%) iodine value (73.41 gI2/100g) acid value (0.78) copper striping corrosion (1a) and calorific value (38.4 MJ/kg) revealed that all quality parameters are within the range specified except for acid value. The fatty acid composition of the biodiesel was also analyzed by Gas chromatography and the major fatty acids found were linoleic acid (39.8%) palmitic acid (37.6%) oleic (12.7%) and stearic acid (7.6%). In addition the solid waste remaining after oil extraction was investigated for possible use as a feedstock for the production of bioethanol. Hydrolysis of the spent was carried out using dilute sulfuric acid followed by fermentation using S. cereviciae and resulted in bioethanol yield of 8.3 %v/v. Furthermore the solid waste remaining after bioethanol production was evaluated for compost and solid fuel applications. The resu