Gas Adsorption in Metal-Organic Frameworks

This text discusses the synthesis characterization and application of metal-organic frameworks (MOFs) for the purpose of adsorbing gases. It provides details on the fundamentals of thermodynamics mass transfer and diffusion that are commonly required when evaluating MOF materials for gas separation and storage applications and includes a discussion of molecular simulation tools needed to examine gas adsorption in MOFs. Additionally the work presents techniques that can be used to characterize MOFs after gas adsorption has occurred and provides guidance on the water stability of these materials. Lastly applications of MOFs are considered with a discussion of how to measure the gas storage capacity of MOFs a discussion of how to screen MOFs to for filtration applications and a discussion of the use of MOFs to perform industrial separations such as olefin/paraffin separations. Throughout the work fundamental information such as a discussion on the calculation of MOF surface area and description of adsorption phenomena in packed-beds is balanced with a discussion of the results from research literature.