Heterophase Polymerization

<p>Heterophase polymerization is a century-old technology with a wide range of relevant industrial applications including coatings adhesives rubbers and many other specialized biomedical and high-performance materials. However due to its multiscale complexity it still remains a challenging research topic. It is a broad field covering all heterogeneous polymerization processes that result in polymer dispersions. Its technical realizations comprise emulsion polymerization dispersion polymerization suspension polymerization miniemulsion polymerization microemulsion polymerization and others. This book is devoted to the science and technology of heterophase polymerization considering it a generic term as well as an umbrella expression for all of its technical realizations. It presents from a modern perspective the basic concepts and principles required to understand the kinetics and thermodynamics of heterophase polymerization at the atomistic molecular macromolecular supramolecular colloidal microscopic mesoscopic and macroscopic scales. It critically discusses the important physicochemical mechanisms involved in heterophase polymerization such as nucleation particle aggregation mass transfer swelling spontaneous emulsification and polymerization kinetics along with the experimental evidences at hand.</p>